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Neutron scattering studies of premartensitic indium-thallium alloys

Identifieur interne : 000532 ( Main/Exploration ); précédent : 000531; suivant : 000533

Neutron scattering studies of premartensitic indium-thallium alloys

Auteurs : RBID : ISTEX:11661_1988_Article_BF02652526.pdf

Abstract

A set of measured phonon dispersion curves for In-Tl at a temperature slightly greater thanjhe structural transformation temperature,Tm, has failed to show phonon softening of the [ζζ0] [ζζ-z0] branch to within ζ = 0.15 of the zone center. To reconcile this with the known softening of the elastic constant, 1/2 (C11 —C12) requires that the dispersion curve show a strong positive curvature at low ζ along this branch. Experiments on a second set of crystals, grown as oriented flat plates, were designed to investigate the [ζζ0] [ζζ-z0] phonons and their temperature dependence in the premartensitic temperature regime. The results from these crystals support the positive curvature at low ζ for the [ζζ0] [ζζ-z0] branch. In addition the low-ζ, [ζζ0] [ζζ-z0] phonons show the normal trend of frequency increasing (hardening) as temperature is decreased toward the transformation temperature, indicating that the phonon softening predicted by the temperature dependence of the elastic modulus, 1/2 (C11 -C12), is confined to smaller phonon wave vectors than can be resolved in the present experiments.

DOI: 10.1007/BF02652526

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<div type="abstract" xml:lang="eng">A set of measured phonon dispersion curves for In-Tl at a temperature slightly greater thanjhe structural transformation temperature,Tm, has failed to show phonon softening of the [ζζ0] [ζζ-z0] branch to within ζ = 0.15 of the zone center. To reconcile this with the known softening of the elastic constant, 1/2 (C11 —C12) requires that the dispersion curve show a strong positive curvature at low ζ along this branch. Experiments on a second set of crystals, grown as oriented flat plates, were designed to investigate the [ζζ0] [ζζ-z0] phonons and their temperature dependence in the premartensitic temperature regime. The results from these crystals support the positive curvature at low ζ for the [ζζ0] [ζζ-z0] branch. In addition the low-ζ, [ζζ0] [ζζ-z0] phonons show the normal trend of frequency increasing (hardening) as temperature is decreased toward the transformation temperature, indicating that the phonon softening predicted by the temperature dependence of the elastic modulus, 1/2 (C11 -C12), is confined to smaller phonon wave vectors than can be resolved in the present experiments.</div>
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<abstract lang="eng">A set of measured phonon dispersion curves for In-Tl at a temperature slightly greater thanjhe structural transformation temperature,Tm, has failed to show phonon softening of the [ζζ0] [ζζ-z0] branch to within ζ = 0.15 of the zone center. To reconcile this with the known softening of the elastic constant, 1/2 (C11 —C12) requires that the dispersion curve show a strong positive curvature at low ζ along this branch. Experiments on a second set of crystals, grown as oriented flat plates, were designed to investigate the [ζζ0] [ζζ-z0] phonons and their temperature dependence in the premartensitic temperature regime. The results from these crystals support the positive curvature at low ζ for the [ζζ0] [ζζ-z0] branch. In addition the low-ζ, [ζζ0] [ζζ-z0] phonons show the normal trend of frequency increasing (hardening) as temperature is decreased toward the transformation temperature, indicating that the phonon softening predicted by the temperature dependence of the elastic modulus, 1/2 (C11 -C12), is confined to smaller phonon wave vectors than can be resolved in the present experiments.</abstract>
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